Search results for "Molecular control"
showing 2 items of 2 documents
Ultrafast optics in coherently spinning molecules
2020
This thesis reports on the study of unidirectional rotation of molecules and focuses on the rotational Doppler effect occuring in the course of third-harmonic generation in coherently spinning molecules.The rotational Doppler effect appears when a circularly polarized wave interacts with an anisotropic rotating object. During the interaction, an exchange of angular momentum and energy between the field and the object occurs, leading to a frequency shift of the wave. In this work, the frequency shift of the third-harmonic generated in unidirectionaly rotating molecules has been observed. An anlytical model developped in the mansucript forsees four kinds of frequency shifts depending on the m…
Qauntum control of molecular rotation and of processes in Nuclear Magnetic Resonance
2019
The goal of this thesis is to apply quantum control techniques to manipulate molecular rotation and to enhance the efficiency of processes in Nuclear Magnetic Resonance.These techniques have been used theoretically and experimentally to control the orientation of a symmetric top molecule by means of THz laser fields. This study has been extended to the case of a long interaction distance between the field and the sample. In this case, the molecule cannot be approximated as isolated. We have also shown the extend to which the time evolution of the degree of orientation can be shaped. Optimal control techniques were used to design the THz field which allows to reach the corresponding dynamics…